Prof. Dr. Feihe Huang

Profile

Academic positionFull Professor
Research fieldsPreparative and Physical Chemistry of Polymers,Organic Molecular Chemistry
Keywordscrown compounds, gel, molecular recognition, stimuli-responsive material, supramolecular chemsitry

Current contact address

CountryPeople's Republic of China
CityHangzhou
InstitutionZhejiang University (ZJU)
InstituteDepartment of Chemistry
Homepagehttp://www.chem.zju.edu.cn/~huangfeihe/index.php

Host during sponsorship

Prof. Dr. Dr. h.c. Markus AntoniettiAbteilung Kolloidchemie, Max-Planck-Institut für Kolloid- und Grenzflächenforschung, Golm
Start of initial sponsorship01/11/2011

Programme(s)

2011Humboldt Research Fellowship Programme for Experienced Researchers

Publications (partial selection)

2011Dong, S.; Luo, Y.; Yan, X.; Zheng, B.; Ding, X.; Yu, Y.; Ma, Z.; Zhao, Q.; Huang, F.* A Dual-Responsive Supramolecular Polymer Gel Formed by Crown Ether-Based Molecular Recognition. In: Angew. Chem., Int. Ed., 2011, 1905-1909
2011Zhang, Z.; Luo, Y.; Xia, B.; Han, C.; Yu, Y.; Chen, X.; Huang, F.*: Four Constitution Isomers of BMpillar[5]arene: Synthesis, Crystal Structures and Complexation with n-Octyltrimethyl Ammonium Hexafluorophosphate. In: Chem. Commun., 2011, 2417-2419
2011Ma, Y.; Zhang, Z.; Ji, X.; Han, C.; He, J.; Zeper, A.; Chen, W.; Huang, F.*: Preparation of Pillar[n]arenes (n = 5 or 6) by Cyclooligomerization of 2,5-Dialkoxybenzyl Alcohols or 2,5-Dialkoxybenzyl Bromides. In: Eur. J. Org. Chem. , 2011, 5331-5335
2011Niu, Z.; Huang, F.; Gibson, H. W.*: Supramolecular AA BB Type Linear Polymers with Relatively High Molecular Weights via the Self-Organization of Bis(meta-phenylene)-32-Crown-10 Cryptands and a Bisparaquat Derivative. In: J. Am. Chem. Soc., 2011, 2836-2839
2011Yan, X.; Zhou, M.; Chen, J.; Chi, X.; Dong, S.; Zhang, M.; Ding, X.; Yu, Y.; Shao, S.; Huang, F.*: Supramolecular Polymer Nanofibers via Electrospinning of a Heteroditopic Monomer. In: Chem. Commun. , 2011, 7086-7088
2011Zhang, M.; Zheng, B.; Huang, F.*: Synthesis of a Four-armed Cage Molecule and Its pH-Controlled Complexation with Paraquat. In: Chem. Commun., 2011, 10103-10105
2011Xia, B.; He, J.; Zeper, A.; Yu, Y.; Huang, F.*: Synthesis of a Pillar[5]arene Dimer by Co-oligomerization and Its Complexation with n-Octyltrimethyl Ammonium Hexafluorophosphate. In: Tetrahedron Lett., 2011, 4433-4436
2011Niu, Z.; Slebodnick, C.; Bonrad, K.; Huang, F.; Gibson, H. W.*: The First [2]Pseudorotaxane and the First Pseudocryptand-Type Poly[2]pseudorotaxane Based on Bis(meta-phenylene)-32-Crown-10 and Paraquat Derivatives. In: Org. Lett. , 2011, 2872-2875
2011Yan, X.; Zhang, M.; Wei, P.; Zheng, B.; Chi, X.; Ji, X.; Huang, F.*: pH-Responsive assembly and Disassembly of a Supramolecular Cryptand-based Pseudorotaxane Driven by p-p Stacking Interaction. In: Chem. Commun., 2011, 9840-9842
2010Li, S.; Chen, J.; Zheng, B.; Dong, S.; Ma, Z.; Gibson, H. W.; Huang, F.*: A Hyperbranched, Rotaxane-Type Mechanically Interlocked Polymer. In: J. Polym. Sci. Pol. Chem., 2010, 4067-4073
2010Li, S.;* Zheng, B.; Huang, F.; Zakharov, L. N.; Slebodnick, C.; Rheingold, A. L.; Gibson, H. W.: A new cryptand/paraquat [2]pseudorotaxane. In: Sci. China Ser. B-Chem., 2010, 858-862
2010Zhu, K.; Wu, L.; Yan, X.; Zheng, B.; Zhang, M.; Huang, F.*: Anion Assisted Complexation of Paraquat by Bis(m-phenylene)-32-crown-10-Based Cryptands. In: Chem. Eur. J. , 2010, 6088-6098
2010Han, C.; Ma, F.; Zhang, Z.; Xia, B.; Yu, Y.; Huang, F.*: DIBPillar[n]arenes (n = 5, 6): Syntheses, X-Ray Crystal Structures, and Complexation with n-Octyltriethyl Ammonium Hexafluorophosphate. In: Org. Lett., 2010, 4360-4363
2010Zhang, Z.; Luo, Y.; Chen, J.; Dong, S.; Yu, Y.; Ma, Z.; Huang, F.*: Formation of Linear Supramolecular Polymers Driven by the C-H•••π Interactions in Solution and in the Solid State. In: Angew. Chem., Int. Ed. , 2010, 1397-1401
2010Zhang, M.; Zhu, K.; Huang, F.*: Improved Complexation of Paraquat Derivatives by the Formation of Crown Ether-Based Cryptands. In: Chem. Commun. , 2010, 8131-8141
2010Zhang, M.; Luo, Y.; Zheng, B.; Yan, X.; Fronczek, F. R.; Huang, F.*: Improved Pseudorotaxane and Catenane Formation from a Derivative of Bis(m-phenylene)-32-crown-10. In: Eur. J. Org. Chem. , 2010, 6798-6803
2010Zhang, M.; Luo, Y.; Zheng, B.; Xia, B.; Huang, F.*: Improved and Controlled Complexation of Paraquat Derivatives by the Formation of A Bis(m-phenylene)-26-crown-8-Based Lariat Ether. In: Eur. J. Org. Chem., 2010, 5543-5547
2010Wang, F.; Zhang, J.; Ding, X.; Dong, S.; Liu, M.; Zheng, B.; Li, S.; Zhu, K.; Wu, L.; Yu, Y.; Gibson, H. W.; Huang, F.*: Metal-Coordination-Mediated Reversible Conversion between Linear and Crosslinked Supramolecular Polymers. In: Angew. Chem., Int. Ed., 2010, 1090-1094
2010Wu, L.; Liu, M.; Chen, X.; Li, S.; Huang, F.*: Negatively Charged Crown Ethers for Binding Paraquat in Water. In: Sci. China Ser. B-Chem., 2010, 1074-1080
2010Liu, M.; Yan, X.; Hu, M.; Chen, X.; Zhang, M.; Zheng, B.; Hu, X.; Shao, S.; Huang, F.*: Photoresponsive Host-Guest Systems Based on a New Azobenzene-Containing Crytpand. In: Org. Lett., 2010, 2558-2561
2010Liu, M.; Li, S.; Hu, M.; Wang, F.; Huang, F.*: Selectivity Algorithm for the Formation of Two Cryptand/Paraquat Catenanes. In: Org. Lett., 2010, 760-763
2010Zhang, Z.; Xia, B.; Han, C.; Yu, Y.; Huang, F.*: Syntheses of Copillar[5]arenes from Co-Oligomerization of Different Monomers. In: Org. Lett., 2010, 3285-3287
2010Zhang, M.; Zheng, B.; Xia, B.; Zhu, K.; Wu, C.; Huang, F.*: Synthesis of A Bis(1,2,3-phenylene) Cryptand and Its Dual-Responsive Binding to Paraquat and Diquat. In: Eur. J. Org. Chem., 2010, 6804-6809
2009Li, S.; Zhu, K.; Zheng, B.; Wen, X.; Li, N.; Huang, F.*: A Bis(m-phenylene)-32-crown-10/Paraquat [2]Rotaxane. In: Eur. J. Org. Chem., 2009, 1053-1057
2009Zhu, K.; Li, S.; Wang, F.; Huang, F.*: Anion-Controlled Ion-Pair Recognition of Paraquat by a Bis(m-phenylene)-32-crown-10 Derivative Heteroditopic Host. In: J. Org. Chem. , 2009, 1322-1328
2009Li, S.; Huang, F.;* Slebodnick, C.; Ashraf-Khorassani, M.; Gibson, H. W.*: Complexes of Diquat with Dibenzo-24-Crown-8. In: Chin. J. Chem. , 2009, 1777-1781
2009Wang, F.; Zhou, Q.; Zhu, K.; Li, S.; Wang, C.; Liu, M.; Li, N.; Fronczek, F. R.; Huang, F.*: Efficient Syntheses of Bis(m-phenylene)-26-crown-8-Based Cryptand/Paraquat [2]Rotaxanes by Immediate Solvent Evaporation Method. In: Tetrahedron, 2009, 1488-1494
2009Wang, F.; Zheng, B.; Zhu, K.; Zhou, Q.; Zhai, C.; Li, S.; Li, N.; Huang, F.*: Formation of Linear Main-Chain Polypseudorotaxanes with Supramolecular Polymer Backbones via Two Self-Sorting Host-Guest Recognition Motifs. In: Chem. Commun. , 2009, 4375-4377
2009Ge, Z.; Hu, J.; Huang, F.;* Liu, S.*: Responsive Supramolecular Gels Constructed by Crown Ether Based Molecular Recognition. In: Angew. Chem. Int. Ed. , 2009, 1798-1802
2009Gibson, H. W.;* Farcas, A.; Jones, J. W.; Ge, Z.; Huang, F.; Vergne, M.; Hercules, D. M.: Supramacromolecular self-assembly: Chain extension, star and block polymers via pseudorotaxane formation from well-defined end-functionalized polymers. In: J. Polym. Sci. Pol. Chem. , 2009, 3518-3543
2009Zhu, K.; He, J.; Li, S.; Liu, M.; Wang, F.; Zhang, M.; Abliz, Z.; Yang, H.; Li, N.; Huang, F.*: Synthesis of Bis(m-phenylene)-32-crown-10-Based Discrete Rhomboids Driven by Metal-Coordination and Complexation with Paraquat. In: J. Org. Chem., 2009, 3909-3912
2009Li, S.; Liu, M.; Zheng, B.; Zhu, K.; Wang, F.; Li, N.; Zhao, X.; Huang, F.*: Taco Complex Templated Syntheses of a Cryptand/Paraquat [2]Rotaxane and [2]Catenane by Olefin Metathesis. In: Org. Lett. , 2009, 3350-3353
2009Liu, M.; Li, S.; Zhang, M.; Zhou, Q.; Wang, F.; Hu, M.; Fronczek, F. R.; Li, N.; Huang, F.*: Three-Dimensional Bis(m-phenylene)-32-crown-10-Based Cryptand/Paraquat Catenanes. In: Org. Biomol. Chem. , 2009, 1288-1291
2008Zhang, J.; Zhai, C.; Wang, F.; Zhang, C.; Li, S.; Zhang, M.; Li, N.; Huang, F.*: A Bis(m-phenylene)-32-crown-10-Based Fluorescence Chemosensor for Paraquat and Diquat. In: Tetrahedron Lett., 2008, 5009-5012
2008Pederson, A. M.-P.; Vetor, R. C.; Rouser, M. A.; Huang, F.; Slebodnick, C.; Schoonover, D. V.; Gibson, H. W.*: A New Functional Bis(m-phenylene)-32-crown-10-Based Cryptand Host for Paraquats. In: J. Org. Chem., 2008, 5570-5573
2008Zhang, C.; Zhu, K.; Li, S.; Zhang, J.; Wang, F.; Liu, M.; Li, N.; Huang, F.*: Binding of secondary dialkylammonium salts by pyrido-21-crown-7. In: Tetrahedron Lett. , 2008, 6917-6920
2008Li, S.; Liu, M.; Zhang, J.; Zheng, B.; Zhang, C.; Wen, X.; Li, N.; Huang, F.*: High-yield preparation of [2]rotaxanes based on the bis(m-phenylene)-32-crown-10-based cryptand/paraquat derivative recognition motif. In: Org. Biomol. Chem., 2008, 2103-2107
2008Zhu, K.; Zhang, M.; Wang, F.; Li, N.; Li, S.; Huang, F.*: Improved Complexation between Dibenzo-24-crown-8 Derivatives and Dibenzylammonium Salts by Ion-Pair Recognition. In: New J. Chem., 2008, 1827-1830
2008Li, S.; Liu, M.; Zhang, J.; Zheng, B.; Wen, X.; Li, N.; Huang, F.*: Preparation of Bis(m-phenylene)-32-crown-10-Based Cryptand/Bisparaquat [3]Rotaxanes with High Efficiency. In: Eur. J. Org. Chem., 2008, 6128-6133
2008Wang, F.; Han, C.; He, C.; Zhou, Q.; Zhang, J.; Wang, C.; Li, N.; Huang, F.*: Self-Sorting Organization of Two Heteroditopic Monomers to Supramolecular Alternating Copolymers. In: J. Am. Chem. Soc., 2008, 11254-11255
2008He, C.; Shi, Z.; Zhou, Q.; Li, S.; Li, N.; Huang, F.*: Syntheses of cis- and trans-Dibenzo-30-crown-10 Derivatives via Regioselective Routes and Their Complexations with Paraquat and Diquat. In: J. Org. Chem., 2008, 5872-5880
2008Zhou, Q.; He, C.; Zhai, C.; Huang, F.*: Templated syntheses of molecules with mechanically interlocked structures. In: Huaxue Tongbao, 2008, 809-815
2007Zhang, C.; Li, S.; Zhang, J.; Zhu, K.; Li, N.; Huang, F.*: Benzo-21-crown-7/Dialkylammonium Salt [2]Pseudorotaxane- and [2]Rotaxane-Type Threaded Structures. In: Org. Lett., 2007, 5553-5556
2007Huang, F.;* Jones, J. W.; Gibson, H. W.*: Competitive Interactions of Two Ion-Paired Salts with a Neutral Host to Form Two Non-Ion-Paired Complexes. In: J. Org. Chem. , 2007, 6573-6576
2007Huang, F.;* Nagvekar, D. S.; Zhou, X.; Gibson, H. W.*: Formation of a Linear Supramolecular Polymer by Self-Assembly of Two Homoditopic Monomers Based on the Bis(m-phenylene)-32-crown-10/Paraquat Recognition Motif. In: Macromolecules, 2007, 3561-3567
2007Zhang, X.; Zhai, C.; Li, N.; Liu, M.; Li, S.; Zhu, K.; Zhang, J.; Huang, F.;* Gibson, H. W.: Host Size Effect in the Complexation of Two Bis(m-phenylene)-32-crown-10-Based Cryptands with a Diazapyrenium Salt. In: Tetrahedron Lett., 2007, 7537-7541
2007Huang, F.;* Slebodnick, C.; Switek, K. A.; Gibson, H. W.*: Inclusion [2]Complexes Based on the Cryptand/Diquat Recognition Motif. In: Tetrahedron, 2007, 2829-2839
2007Zhang, J.; Huang, F.;* Li, N.; Wang, H.; Gibson, H. W.;* Gantzel, P.; Rheingold, A. L.: Paraquat Substituent Effect on Complexation with a Dibenzo-24-crown-8-Based Cryptand. In: J. Org. Chem., 2007, 8935-8938
2007Huang, F.;* Slebodnick, C.; Mahan, E. J.; Gibson, H. W.*: [3]Pseudorotaxanes Based on the Cryptand/Monopyridinium Salt Recognition Motif. In: Tetrahedron, 2007, 2875-2881
2006Huang, F.;* Slebodnick, C.; Switek, K. A.; Gibson, H. W.*: Bis(m-phenylene)-32-crown-10-Based Cryptand/Diquat Inclusion [2]Complexes. In: Chem. Commun. , 2006, 1929-1931
2006Huang, F.;* Yang, H.-B.; Das, N.; Maran, U.; Arif, A. M.; Gibson, H. W.; Stang, P. J.: Incorporating a Flexible Crown Ether into Neutral Discrete Self-Assemblies Driven by Metal-Coordination. In: J. Org. Chem., 2006, 6223-6225
2006Yang, H.-B.; Das, N.; Huang, F.; Hawkridge, A. M.; Diaz, D. D.; Arif, A. M.; Finn, M. G.; Muddiman, D. C.; Stang, P. J.*: Incorporation of 2,6-Di(4,4'-dipyridyl)-9-thiabicyclo[3.3.1]nonane into Discrete 2D Supramolecules via Coordination-Driven Self-Assembly. In: J. Org. Chem. , 2006, 6644-6647
2006Yang, H.-B.; Das, N.; Huang, F.; Hawkridge, A. M.; Muddiman, D. C.; Stang, P. J.*: Molecular Architecture via Coordination: Self-Assembly of Nanoscale Hexagonal Metallodendrimers with Designed Building Blocks. In: J. Am. Chem. Soc., 2006, 10014-10015
2006Huang, F.;* Gantzel, P.; Nagvekar, D. S.; Rheingold, A. L.; Gibson, H. W.*: Taco Grande: a Dumbbell Bis(crown ether)/Paraquat [3](Taco Complex). In: Tetrahedron Lett. , 2006, 7841-7844
2005Huang, F.; Slebodnick, C.; Ratliff, A.; Gibson, H. W.*: A Bis(m-phenylene)-32-crown-10/Monopyridinium [2]Pseudorotaxane. In: Tetrahedron Lett., 2005, 6019-6022
2005Huang, F.; Gibson, H. W.* A Supramolecular Poly[3]pseudorotaxane from Self-Assembly of a Homoditopic Cylindrical Bis(crown ether) Host and a Bisparaquat Derivative. In: Chem. Commun. , 2005, 1696-1698
2005Huang, F.; Nagvekar, D. S.; Slebodnick, C.; Gibson, H. W.*: A Supramolecular Triarm Star Polymer from a Homotritopic Tris(Crown Ether) Host and a Complementary Monotopic Paraquat-Terminated Polystyrene Guest by a Supramolecular Coupling Method. In: J. Am. Chem. Soc., 2005, 484-485
2005Huang, F.; Switek, K. A.; Zakharov, L. N.; Fronczek, F. R.; Slebodnick, C.; Lam, M.; Golen, J. A.; Bryant, W. S.; Mason, P.; Rheingold, A. L.; Ashraf-Khorassani, M.; Gibson, H. W.*: Bis(m-phenylene)-32-crown-10-Based Cryptands, Powerful Hosts for Paraquat Derivatives. In: J. Org. Chem., 2005, 3231-3241
2005Huang, F.; Gibson, H. W.*: Polypseudorotaxanes and Polyrotaxanes. In: Prog. Polym. Sci., 2005, 982-1018
2005Huang, F.; Lam, M.; Mahan, E. J.; Rheingold, A. L.; Gibson, H. W.*: Promotion of Host Folding during the Formation of a Taco Complex. In: Chem. Commun., 2005, 3268-3270
2005Huang, F.; Guzei, I. A.; Jones, J. W.; Gibson, H. W.*: Remarkably Improved Complexation of a Bisparaquat by Formation of a Pseudocryptand-Based [3]Pseudorotaxane. In: Chem. Commun., 2005, 1693-1695
2005Huang, F.; Fronczek, F. R.; Ashraf-Khorassani, M.; Gibson, H. W.*: Slow-Exchange C3-Symmetric Cryptand/Trispyridinium Inclusion Complexes Containing Nonlinear Guests: A New Type of Threaded Structure. In: Tetrahedron Lett., 2005, 6765-6769
2005Gibson, H. W.;* Ge, Z.; Huang, F.; Jones, J. W.; Lefebvre, H.; Vergne, M. J.; Hercules, D. M.: Syntheses and Model Complexation Studies of Well-Defined Crown Terminated Polymers. In: Macromolecules , 2005, 2626-2637
2005Huang, F.; Zakharov, L. N.; Rheingold, A. L.; Ashraf-Khorassani, M.; Gibson, H. W.*: Synthesis of a Symmetric Cylindrical Bis(crown ether) Host and Its Complexation with Paraquat. In: J. Org. Chem., 2005, 809-813
2005Huang, F.; Slebodnick, C.; Rheingold, A. L.; Switek, K. A.; Gibson, H. W.*: [2]Pseudorotaxanes Based on the Cryptand/Monopyridinium Recognition Motif. In: Tetrahedron, 2005, 10242-10253
2005Huang, F.; Switek, K. A.; Gibson, H. W.*: pH-Controlled assembly and disassembly of a cryptand/paraquat [2]pseudorotaxane. In: Chem. Commun., 2005, 3655-3657
2004Jones, J. W.; Huang, F.; Bryant, W. S.; Gibson, H. W.*: A Cautionary Note Regarding the Investigation of Supramolecular Complexes Involving Secondary Ammonium Salts in Acetone. In: Tetrahedron Lett., 2004, 5961-5963
2004Huang, F.; Gibson, H. W.*: Formation of a Supramolecular Hyperbranched Polymer from Self-Organization of an AB2 Monomer Containing a Crown Ether and Two Paraquat Moieties. In: J. Am. Chem. Soc., 2004, 14738-14739
2004Huang, F.; Zhou, L.; Jones, J. W.; Gibson, H. W.;* Ashraf-Khorassani, M.: Formation of dimers of inclusion cryptand/paraquat complexes driven by dipole-dipole and face-to-face -stacking interactions. In: Chem. Commun., 2004, 2670-2671
2003Huang, F.; Fronczek, F. R.; Gibson, H. W.*: A Cryptand/Bisparaquat [3]Pseudorotaxane by Cooperative Complexation. In: J. Am. Chem. Soc., 2003, 9272-9273
2003Huang, F.; Gibson, H. W.;* Bryant, W. S.; Nagvekar, D. S.; Fronczek, F. R.: First Pseudorotaxane-Like [3]Complexes Based on Cryptands and Paraquat: Self-Assembly and Crystal Structures. In: J. Am. Chem. Soc. , 2003, 9367-9371
2003Huang, F.; Fronczek, F. R.; Gibson, H. W.*: First Supramolecular Poly(taco complex). In: Chem. Commun., 2003, 1480-1481
2003Huang, F.; Jones, J. W.; Slebodnick, C.; Gibson, H. W.*: Ion Pairing in Fast-Exchange Host-Guest Systems: Concentration Dependence of Apparent Association Constants for Complexes of Neutral Hosts and Divalent Guest Salts with Monovalent Counterions. In: J. Am. Chem. Soc., 2003, 14458-14464
2003Gibson, H. W.;* Ge, Z. Huang, F.; Jones, J. W.; Wang, H.; Farcas, A.: Mechanically Interlocked Macromolecular Systems via Pseudorotaxane Self-assembly. In: Polymer Preprints, 2003, 475-476
2003Huang, F.; Zakharov, L. N.; Rheingold, A. L.; Jones, J. W.; Gibson, H. W.*: Water Assisted Formation of a Pseudorotaxane and Its Dimer Based on a Supramolecular Cryptand. In: Chem. Commun., 2003, 2122-2123